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The combination of pyrolysis and CO2 gasification was studied to synergistically improve the syngas yield and biochar quality. The subsequent 60-min CO2 gasification at 800 C after pyrolysis increased the syngas yield from 23.4% to 40.7% while decreasing the yields of biochar and bio-oil from 27.3% to 17.1% and from 49.3% to 42.2%, respectively. The BET area of the biochar obtained by the subsequent 60-min CO2 gasification at 800 C was 384.5 m2 /g, compared to 6.8 m2 /g for the biochar obtained by the 60- min pyrolysis at 800 C, and 1.4 m2 /g for the raw biomass. The biochar obtained above 500 C was virtually amorphous.more » « less
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Eshun, John; Wang, Lijun; Ansah, Emmanuel; Shahbazi, Abolghasem; Schimmel, Keith; Kabadi, Vinayak; Aravamudhan, Shyam (, Journal of the Energy Institute)
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